Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation
Matthew J. Harper†, Edward J. Emmett, John F. Bower , and Christopher A. Russell
School of Chemistry, University of Bristol, Bristol BS8 1TS, United Kingdom
Syngenta, Jealott’s Hill International Research Centre, Bracknell, Berkshire RG42 6EY, United Kingdom
Syngenta, Jealott’s Hill International Research Centre, Bracknell, Berkshire RG42 6EY, United Kingdom
Link:J. Am. Chem. Soc., 2017, 139 (36), pp 12386–12389
DOI: 10.1021/jacs.7b06668
Publication Date (Web): August 22, 2017
Abstract
Under the conditions of oxidative gold catalysis, exposure of ethylene to aryl silanes and alcohols generates products of 1,2-oxyarylation. This provides a rare example of a process that allows catalytic differential 1,2-difunctionalization of this feedstock chemical.
DOI: 10.1021/jacs.7b06668
Publication Date (Web): August 22, 2017
Abstract
Under the conditions of oxidative gold catalysis, exposure of ethylene to aryl silanes and alcohols generates products of 1,2-oxyarylation. This provides a rare example of a process that allows catalytic differential 1,2-difunctionalization of this feedstock chemical.
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